高性能细晶钨及钨合金的研究进展Advances in Fine Grained Tungsten and Tungsten Alloys with High Performance
范景莲;李鹏飞;刘涛;韩勇;吕永齐;
摘要(Abstract):
高性能钨及钨合金是国防工业和尖端技术领域中的关键材料,新的制备技术使钨材料在致密度、组织均匀性、力学性能及物理性能等方面有了明显提高。综述了国内外采用纳米复合技术制备细晶W-Ni-Fe合金、细晶WCu材料、高致密细晶纯钨材料,以及采用微纳复合技术制备稀土氧化物和碳化物增强细晶钨的研究进展,分析了目前制备过程中存在的问题,并进一步展望了高性能钨及钨合金材料的发展趋势和应用前景。
关键词(KeyWords): 高性能钨合金;细晶;组织均匀性;纳米复合技术;微纳复合技术
基金项目(Foundation): 国家科技部重大专项(2014GB115000);; 教育部博士点基金(20130162130002)
作者(Authors): 范景莲;李鹏飞;刘涛;韩勇;吕永齐;
参考文献(References):
- [1]FAN J L,GONG X,HUANG B Y,et al.Densification behavior of nanocrystalline W-Ni-Fe composite powder prepared by sol-spray drying and hydrogen reduction process[J].Journal of Alloys and Compounds,2010,489(1):188-194.
- [2]WANG W F.Effect of tungsten particle size and copper content on working behavior of W-Cu alloy electrodes during elect rodischarge machining[J].Powder Metallurgy,1997,40(4):295-300
- [3]SRIKANTH R,DAVID L,BOURELL.Synthesis and evaluation of advanced nanocrystalline Tungsten-based Materials[J].P/M Science and Techenology Briefs,1999,1(1):9-14.
- [4]FAN J L,HUANG B Y.Densification and microstructure characteristics of mechanically alloyed W-Ni-Fe powders[J].Journal of Advanced Materials,2004,36(4):48-52.
- [5]FAN J L,LIU T,HUANG B Y,et al.Preparation and sintering of nanosized W-Ni-Fe powder by sol-spray drying process[J].Materials Science Forum,2007,(534/536):1409-1412.
- [6]FAN J L,LIU T,CHENG H C,et al.Preparation of fine grain tungsten heavy alloy with high properties by mechanical alloying and yttrium oxide addition[J].Journal of Materials Processing Technology,2008,208(1/3):463-469.
- [7]张丽英,吴庆华,吴成义,等.W-Ni-Fe系纳米级复合氧化物粉末的制取及粉末特性[J].北京科技大学学报,1998,20(4):326-330.ZHANG Li-ying,WU Qing-hua,WU Cheng-yi,et al.Making WNi-Fe system nanomic composite oxied power and its futures[J].Journal of University of Science and Technology Beijing,1998,20(4):326-330.
- [8]范景莲,曲选辉,李益民,等.高比重合金的固相烧结[J].中国有色金属学报,1999,9(2):327-329.FAN Jing-lian,QU Xuan-hui,LI Yi-min,et al.Solid-state sintering of tungsten heavy alloy[J].The Chinese Journal of Nonferrous Metals,1999,9(2):327-329.
- [9]祁美贵,范景莲,张骁,等.微量Y2O3对细晶W-Ni-Fe粉末烧结行为和显微组织的影响[J].中国有色金属学报,2009,19(4):656-661.QI Mei-gui,FAN Jing-lian,ZHANG Xiao,et al.Influence of trace Y2O3on sintering behavior and microstructure of fine-grain WNi-Fe powders[J].The Chinese Journal of Nonferrous Metals,2009,19(4):656-661.
- [10]曾毅,范景莲,龚星,等.纳米晶W-Ni-Fe复合粉末烧结过程中的致密化与显微组织演变[J].中南大学学报:自然科学版,2011,42(7):1906-1911.ZENG Yi,FAN Jing-lian,GONG Xing,et al.Densification and microstructure evolution of nanocrystalline W-Ni-Fe composite powders during sintering[J].Journal of Central South University,2011,42(7):1906-1911.
- [11]范景莲,曾毅,刘涛,等.纳米晶W-Ni-Fe复合粉末及其烧结过程中的固溶特性[J].稀有金属材料科学与工程,2011,40(7):1234-1238.FAN Jing-lian,ZENG Yi,LIU Tao,et al.Solid Solution Characteristics of Nano-crystalline W-Ni-Fe Powders during the Preparation and Sintering Processes[J].Rare Metal Materials and Engineering,2011,40(7):1234-1238.
- [12]GONG X,FAN J L,DING F,et al.Microstructure and highly enhanced mechanical properties of fine-grained tungsten heavy alloy after one-pass rapid hot extrusion[J].Materials Science and Engineering A,2011,528(10/11):3646-3652.
- [13]UPADHYAYA A,TIWARI S K,MISHRA P.Microwave sintering of W-Ni-Fe alloy[J].Scripta Materialia,2007,(56):5-8.
- [14]LEE K H,CHA S I,RYU H J,et al.Effect of two-stage sintering process on microstructure and mechanical properties of ODS tungsten heavy alloy[J].Materials Science and Engineering A,2007,(458):323-329.
- [15]范景莲,朱松,刘涛,等.超细/纳米W-20Cu复合粉末的液相烧结机制[J].中国有色金属学报,2011,21(7):1587-1593.FAN Jing-lian,ZHU Song,LIU Tao,et al.Mechanism of ultrafine/nano W-20Cu composite powder during liquid sintering[J].The Chinese Journal of Nonferrous Metals,2011,21(7):1587-1593.
- [16]范景莲,朱松,刘涛,等.溶胶-喷雾干燥W-10Cu和W-20Cu复合粉末的烧结与组织性能研究[J].粉末冶金技术,2011,29(1):1-8.FAN Jing-lian,ZHU Song,LIU Tao,et al.Sintering,microstructure and properties of W-10Cu/W-20Cu composite powders synthesized by sol-spray drying[J].Powder Metallurgy Technology,2011,29(1):1-8.
- [17]赵放,林涛,张丽英,等.超细晶粒W-40%Cu合金的烧结和力学性能[J].北京科技大学学报,2007,27(5):577-581.ZHAO Fang,LIN Tao,ZHAGN Li-ying,et al.Sintering and mechanical properties of nanoscaled W-40%Cu alloys[J].Journal of University of Science and Technology Beijing,2007,27(5):577-581.
- [18]LIN T,ZHAO F,ZHANG L Y,et al.Fine grain tungsten produced with nanoscale powder[J].Journal of University of Science and Technology Beijing,2005,12(3):277-280.
- [19]RYU T,HWANG K S,CHOI Y J,et al.The sintering behavior of nanosized tungsten powder prepared by a plasma process[J].International Journal of Refractory Metals and Hard Materials,2009,(27):701-704.
- [20]WANG H T,FANG Z Z,HWANG K S,et al.Sinter-ability of nanocrystalline tungsten powder[J].International Journal of Refractory Metals and Hard Materials,2010,(28):312-316.
- [21]BATTABYAL M,SCHAUBLIN R,SPATIG P,et al.W-2wt%Y2O3composite:microstructure and mechanical roperties[J].Materials Science and Engineering:A,2012,538:53-57.
- [22]VELEVA L,SCHAUBLIN R,PLOCINSKI T,et al.Processing and characterization of a W-2Y material for fusion power reactors[J].A咬A咬A咬Fusion Engineering and Design,2011,(86):2450-2453.
- [23]AGUIRRE M V,MARTIN A,PASTOR J Y,et al.Mechanical properties of tungsten alloys with Y2O3and Ti additions[J].Journal of Nuclear Materials,2011,(417):516-519.
- [24]MAZHER A Y,SVERKER W,HANS B,et al.Chemically produced nanostructured ODS-lanthanum oxide-tungsten composites sintered by spark plasma[J].Journal of Nuclear Materials,2011,(408):129-135.
- [25]KURISHITA H,AMANO Y,KOBAYASHI S,et al.Development of ultra-fine grained W-Ti C and their mechanical properties for fusion applications[J].Journal of Nuclear Materials,2007,(367/370):1453-1457.
- [26]KURISHITA H,MATSUO S,ARAKAWA H,et al.Superplastic deformation in W-0.5wt.%Ti C with approximately 0.1μm grain size[J].Materials Science and Engineering A,2008,477(1/2):162-167.
- [27]KURISHITA H,MATSUO S,ARAKAWA H,et al.High temperature tensile properties and their application to toughness enhancement in ultra-fine grained W-(0-1.5)wt%Ti C[J].Journal of Nuclear Materials,2009,(386/388):579-582.
- [28]KURISHITA H,KOBAYASHI S,NAKAI K,et al.Development of ultra-fine grained W-(0.25-0.8)wt%Ti C and its superior resistance to neutron and 3 Me V He-ion irradiations[J].Journal of Nuclear Materials,2008,(377):34-40.
- [29]于福文,吴玉程,陈勇,等.W-10%Ti C复合材料的制备与力学性能研究[J].稀有金属,2008,32(2):151-155.YU Fu-wen,WU Yu-cheng,CHEN Yong,et al.Study on preparation and mechanical properties of W-10%Ti C composities[J].Chinese Journal of Rare Metals,2008,32(2):151-155.
- [30]种法力,于福文,陈俊凌.W-Ti C合金面对等离子体材料及其电子束热负荷试验研究[J].稀有金属材料与工程,2010,39(4):750-753.ZHONG Li-fa,YU Fu-wen,CHEN Jun-lin.W-Ti C alloy plasma facing materials and heat flux performance test under electron beam facility[J].Rare Metal Materials and Engineering,2010,39(4):750-753.
- [31]KIM J H,PARK C,LIM J,et al.Microstructures and properties of ultrafine grained W-Zr C composites[J].Alloys compd,2015,(623):282-289.
- [32]KIM J H,SEO M,KANG S.Effect of carbide particle size on the properties of W-Zr C composites[J].International Journal of Refractory Metals and Hard Materials,2010,(527):4021-4027.
- [33]ROOSTA M,BAHARVANDI H.The change occurred in W/Zr C composite properties by using nano reactants[J].International Journal of Refractory Metals and Hard Materials,2013,(37):29-32.
- [34]ROOSTA M,BAHARVANDI H.The comparison of W/Cu and W/Zr C composites fabricated through hot-press[J].International Journal of Refractory Metals and Hard Materials,2010,(28):587-592.
- [35]SONG G M,WANG Y J,ZHOU Y.The mechanical and thermophysical properties of Zr C/W composites at elevated temperature[J].Materials Science and Engineering A,2002,(334):223-232.
- [36]ZHANG T Q,WANG Y J,ZHOU Y,et al.Effect of heat treatment on microstructure and mechanical properties of Zr C particles reinforced tungsten-matrix composites[J].Materials Science and Engineering A,2009,(512):19-25.
- [37]ZHANG T Q,WANG Y J,ZHOU Y,et al.Effect of Zr C particle size on microstructure and room temperature mechanical properties of Zr Cp/W composites[J].Mater Sci Eng A,2010,(527):4021-4027.
- [38]FAN J L,HAN Y,LI P F,et al.Micro/nano composited tungsten material and its high thermal loading behavior[J].Journal of Nuclear Materials,2014,(455):717-723.