Cr3C2和VC复合抑制剂对超细WC-9%Co硬质合金制备及性能的影响Effect of Cr3C2 and VC Composite Inhibitor on the Preparation and Properties of Ultrafine WC-9 % Co Cemented Carbides
张钱伟,廖军,叶潇潇,叶红云,张玉琪,董凯林
摘要(Abstract):
针对超细晶WC-Co硬质合金的制备,WC晶粒生长抑制剂的运用尤为重要。本研究采用粉末冶金方法制备了超细WC-9%Co硬质合金,研究了Cr_3C_2和VC复合抑制剂对超细WC-9%Co硬质合金制备、微结构及性能的影响。结果表明:随着复合抑制剂中VC的增加,即Cr_3C_2的减少,合金的晶粒尺寸、断裂韧性逐渐降低,矫顽磁力、钴磁逐渐升高,横向断裂强度则先增高后降低;同时,随着VC配比的增加到一定程度合金逐渐出现VC偏析现象。综合来看,WC-9%Co-0.5%Cr_3C_2-0.5%VC超细硬质合金表现出较优的综合物理性能(矫顽磁力38.9 kA/m、钴磁7.82%、密度14.44 cm~3/g)、力学性能(洛氏硬度94.0 HRA、维氏硬度2 010 HV30、横向断裂强度4 691 MPa)。
关键词(KeyWords): 超细晶硬质合金;晶粒生长抑制剂;显微结构;物理性能;力学性能
基金项目(Foundation):
作者(Author): 张钱伟,廖军,叶潇潇,叶红云,张玉琪,董凯林
参考文献(References):
- [1]羊求民,羊建高,苏伟,等.纳米/超细晶WC-Co类硬质合金的研究进展[J].稀有金属与硬质合金,2018,46(1):76–83.YANG Qiumin,YANG Jiangao,SU Wei,et al. Research progress of nano/ultrafine WC-Co cemented carbides[J]. Rare Metals and Cemented Carbides,2018,46(1):76–83.
- [2]张钱伟,倪莹驰,时凯华,等. Co类型对微缺碳WC-6%Co硬质合金的微结构及性能的影响[J].四川冶金,2022,44(4):35–39.ZHANG Qianwei,NI Yingchi,SHI Kaihua,et al. Effect of Co type on microstructure and properities of WC-6%Co cemented carbieds with micro-deficient carbon[J]. Sichuan Metallurgy,2022,44(4):35–39.
- [3]徐海阳,龙波勇,吴金销,等.高压辊磨机硬质合金柱钉应用研究[J].现代矿业,2023,39(7):196–199.XU Haiyang,LONG Boyong,WU Jinxiao,et al. Application research on cemented carbide column nail of high pressure roller mill[J]. Modern Mining,2023,39(7):196–199.
- [4]杨巍,周元莉,羌俊杰,等. Co-Mo-Ni复合粘结相WC基硬质合金刀具干切TC4钛合金切削性能研究[J].工具技术,2023,57(5):58–61.YANG Wei,ZHOU Yuanli,QIANG Junjie,et al. Study on cutting performance of WC-(Co-Mo-Ni)cemented carbide tool in dry turning of CT4 titanium alloy[J]. Tool Engineering,2023,57(5):58–61.
- [5]薛艺,田青超.硬质合金切削刀具研究进展[J].材料导报,2019,33(增刊1):353–357.XUE Yi,TIAN Qingchao. Research progress on cemented carbide cut tools[J]. Materials Reports,2019,33(supply1):353–357.
- [6]王倩玉,秦明礼,吴昊阳,等.新型纳米晶硬质合金的研究现状及发展趋势[J].粉末冶金技术,2022,40(4):362–375.WANG Qianyu,QIN Mingli,WU Haoyang,et al. Research status and development trend of new nanocrystalline cemented carbides[J]. Powder Metallurgy Technology,2022,40(4):362–375.
- [7]李萌,弓满锋,张程煜,等.超细、纳米晶WC-Co硬质合金烧结技术的研究现状[J].材料导报,2020,34(15):15138–15144.LI Meng,GONG Manfeng,ZHANG Chengyu,et al. Research progress of sintering technique of ultrafine and nano WC-Co cemented carbides[J]. Materials Reports,2020,34(15):15138–15144.
- [8] GEOFFREY E. A History of Fine Grained Hardmetal[J].International Journal of Refractory Metals and Hard Materials,1995,13:241–255.
- [9]董凯林,时凯华,顾金宝,等.抑制剂在硬质合金中的应用及研究现状[J].稀有金属与硬质合金,2019,47(4):76–82.DONG Kailin,SHI Kaihua,GU Jinbao,et al. Application and research status of inhibitors in cemented carbides[J]. Rare Metals and Cemented Carbides,2019,47(4):76–82.
- [10] JIANG Hao,ZHAO Zhiwei,QIAN Yanju,et al. Effects of nanocomposite grain growth inhibitors and multi-walled carbon nanotubes on the microstructure and mechanical properties of ultrafine cemented carbides[J]. Journal of Materials Research and Technology,2023,26:3054–3069.
- [11] WANG Kaifei, YANG Xiaohui, DENG Xiaochun, et al.Enhancement of the mechanical properties of ultrafine-grained WC-Co cemented carbides via the in-situ generation of VC[J].Journal of Alloys and Compounds,2022,903:163961.
- [12] YAMAMOTO T,IKUHARA Y,SAKUMA T. High resolution transmission electron microscopy study in VC-doped WC–Co compound[J]. Science and Technology of Advanced Materials,2000,1:97–104.
- [13] POETSCHKE J, RICHTER V, HOLKE R. Influence and effectivity of VC and Cr3C2 grain growth inhibitors on sintering of binderless tungsten carbide[J]. International Journal of Refractory Metals and Hard Materials,2012,31:218–223.
- [14] P?TSCHKE J,RICHTER V,GESTRICH T,et al. Grain growth inhibition in ultrafine hardmetals[J]. International Journal of Refractory Metals and Hard Materials,2017,66:95–104.
- [15] OKADA K,OSADA A. Microstructural study on the grain growth inhibition of VC-doped WC-Co cemented carbides[J].International Journal of Refractory Metals and Hard Materials,2017,62:149–154.
- [16]邱友绪,李宁,张伟,等. WC-Co超细晶硬质合金晶粒长大抑制剂及其机理的研究[J].硬质合金,2006,23(4):254–257.QIU Youxu,LI Ning,ZHANG Wei,et al. Study on grain growth inhibitor and its mechanism of WC-Co ultra-fine crystal cemented carbide[J]. Cemented Carbides,2006,23(4):254–257.
- [17] ZHANG Qianwei,SHI Kaihua,GU Jinbao,et al. Effect of carbon content near the decarbonization phase boundary on the physical and mechanical properties of wc–6%co cemented carbides[J]. Journal of Superhard Materials,2022,44(5):350–357.
- [18]李晨辉,余立新,熊惟皓. WC的粒度对WC-Co硬质合金断裂韧性的影响[J].硬质合金,2001,18(3):138–141.LI Chenhui,YU Lixin,XIONG Weihao. Effect of WC particle size on WC-Co cemented carbides fracture toughness[J].Cemented Carbides,2001,18(3):138–141.
- [19]聂洪波.超粗晶WC-Co硬质合金的制备方法与机理及性能研究[J].中国钨业,2016,31(4):51–57.NIE Hongbo. The preparation, preparation mechauism and properties of extra coarse-grained WC-Co hardmetals[J]. China Tungsten Industry,2016,31(4):51–57.
- [20] HE Meng,WANG Jianyin,HE Rengui,et al. Effect of cobalt content on the microstructure and mechanical properties of coarse grained WC-Co cemented carbides fabricated from chemically coated composite powder[J]. Journal of Alloys and Compounds,2018,766:556–563
- [21]汤昌仁,梁瑜,郭永忠,等.粉末粒度对超粗晶硬质合金性能影响的研究[J].中国钨业,2019,34(4):41–46.TANG Changren,LIANG Yu,GUO Yongzhong,et al. Effect of powder particle size on the properties of ultra-coarse grained cemented carbide[J]. China Tungsten Industry,2019,34(4):41–46.
- [22] CHEN Hao,YANG Qiumin,YANG Jiangao,et al. Effects of VC/Cr3C2 on WC grain morphologies and mechanical properties of WC-6wt.%Co cemented carbides[J]. Journal of Alloys and Compounds,2017,714:245–250.
- [23] YIN Chao,PENG Yingbiao,RUAN Jianming,et al. Influence of Cr3C2 and VC content on WC grain size,WC shape and mechanical properties of WC-6.0 wt.%Co cemented carbides[J].Materials,2021,14(6):1551.